ArXiv · 2026
Ferroelectric memristive devices based on hafnia are promising systems for neuromorphic electronics, yet the interplay between polarization-modulated resistive changes and defect-mediated transport often leads to complex and debated switching mechanisms. Here, we investigate this competition in epitaxial Hf_(0.5)Zr_(0.5)O₂/La_(0.67)Sr_(0.33)MnO₃ heterostructures with Pt top electrodes, by combining structural, ferroelectric, and memristive characterization with a statistical analysis across a broad range of device areas spanning three orders of magnitude. We identify two distinct memristive regimes with opposite resistance-voltage chiralities. Small devices exhibit a low-resistance state that scales inversely with area, consistent with area-distributed electronic transport, while larger devices display an area-independent resistance indicative of localized conductive channels. A statistical nucleation model quantitatively captures this behavior and yields a crossover characteristic area A^* ≈ 10³ μm². This crossover also correlates with the onset of ferroelectric wake-up for the larger devices, linking conductive-channel nucleation and oxygen-vacancy redistribution within a unified physical picture. These results establish lateral device size as a key parameter controlling the dominant transport mechanism in epitaxial hafnia-based devices.
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