ArXiv · 2026
We report profound impacts of the stacking sequence of triangular lattices of magnetic transition metal ions intercalated between the layers of the van der Waals material NbS₂. Using single crystal x-ray and neutron diffraction, and transport and magnetization measurements, we show there are two distinct polytypes of rm V_(1/3)NbS₂ with disparate easy axes of magnetization and different anomalous Hall responses. Self-consistent analysis of inelastic neutron scattering data provides evidence for oscillatory RKKY interactions that extend to 1 nm and stabilize quasi-collinear A-type altermagnetic orders in both polytypes though with perpendicular easy axes. The detailed stacking sequence of a bulk polytype crystal dramatically impact its macroscopic anomalous Hall response and magnetism, which suggests a new path to engineer the bulk properties of a layered three dimensional solid.
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