ArXiv · 2026
Detecting and mapping spin noise can reveal spatial variations in surface defect states, catalytic residues, free radicals, and spintronic materials. However, bulk measurements average over spatial heterogeneity, while scanning-probe maps require sequential rastering. Here, we demonstrate a microwave-free magnetic quenching (MQ) method for wide-field spin-noise mapping using nitrogen-vacancy (NV) centres in diamond. The protocol combines continuous LED illumination with a low-frequency, amplitude-modulated magnetic field, avoiding resonant microwave delivery or pulsed optical hardware. Field-induced spin-state mixing reduces NV photoluminescence, providing the primary contrast mechanism. We examine the response as a function of optical power and magnetic modulation amplitude, interpreting the results using a spin-state mixing model. The method is validated with aqueous gadobutrol concentration series, showing trends consistent with optically detected magnetic resonance (ODMR) measurements. We map spin-noise variations across boron nitride and single-walled carbon nanotube samples with differing defect and metallic catalyst contributions, supported by electron microscopy and spectroscopy. Notably, MQ detects a spin-noise response in boron nitride nanotubes that is silent in bulk EPR spectroscopy. This approach provides a practical framework for spatially resolved spin-noise sensing across quantum technologies and advanced functional materials.
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