Momentum microscopy records the three-dimensional momentum distribution of photoelectrons emitted from a solid sample and, by utilizing sufficiently high photon energies in the ultraviolet spectral range, offers direct access to the electronic band structure of a material. By employing a pump-probe scheme, this method provides a femtosecond view of light-matter interaction and the subsequent relaxation and transport dynamics in a broad range of material systems. However, momentum microscopy has so far been mostly limited to flat and spatially extended surfaces. Photoelectron emission from different three-dimensional facets, in combination with inhomogeneous electric fields around these structures, makes the analysis of the momentum distribution significantly more challenging. Here, we extend the state-of-the-art to a substantially more complex structure and show that a careful analysis of the electron distribution recorded with a momentum microscope provides rich information about both the spatial and momentum distributions on a few-nm and few-mÅ⁻¹ scale, respectively. Combined with prior knowledge of the three-dimensional structure, momentum-resolved photoelectrons can be assigned to nano-localized emission spots, permitting a new level of insight into spatio-temporal charge carrier dynamics.