Orbital angular momentum (OAM) characterization is central to understanding quantum materials such as valley Hall and Rashba systems and, through its connection to Berry curvature, provides key insight into band topology. Conventional OAM detection via photoemission dichroism, however, is susceptible to interference artifacts and is largely restricted to occupied states. Here, we demonstrate a real-space approach to map the L_z OAM character using scanning tunneling microscopy in triangular atomic monolayers. Unlike photoemission, this method exploits interference effects arising from the L_z orbital phase and the Bloch phase associated with neighboring atoms. This shifts the local density of states (LDOS) maxima to distinct Wyckoff positions between atoms, encoding L_z information into characteristic real-space LDOS patterns. We exemplify this approach in 2D quantum materials with contrasting L_z sequences, namely Tl/Si(111) and In/SiC(0001) monolayers, identifying L_z-dependent LDOS accumulation associated with distinct topological phases in both systems. Our results establish L_z-dependent charge localization as a proxy to atomic obstruction for energetically isolated states in triangular lattices, including transition-metal dichalcogenides.