ArXiv · 2026
Solid-state triplet-triplet annihilation upconversion offers a compelling route to harvest sub-bandgap photons to increase the efficiency of photovoltaics, but low sensitizer doping required to suppress non-radiative aggregation quenching severely restricts light absorption. Here, we present a dual-resonator planar silver microcavity housing a thermally co-evaporated rubrene:palladium phthalocyanine (PdPC) active layer designed to simultaneously enhance triplet-sensitizer absorption and out-couple upconverted emission. By aligning a dispersive cavity mode with the PdPC absorption peak at 32^∘, we achieve a 12-fold enhancement in absorptance at 665 nm. This absorption boost, combined with directional outcoupling through a second cavity mode, outweighs cavity-induced reabsorption losses to yield a 22-fold peak and 4.5-fold integrated enhancement in detected upconversion emission. Overall, this work highlights the potential of microcavity integration to substantially enhance solid-state upconversion performance across low-intensity optoelectronic applications.
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